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NIOSH

ACENAPHTHENE

ICSC: 1674

1,2-Dihydroacenaphthylene
1,8-Ethylenenaphthalene
C12H10
Molecular mass: 154.2
ICSC # 1674 		CAS # 83-32-9
RTECS # AB1000000
UN # 3077
October 12, 2006 Validated

TYPES OF HAZARD/ EXPOSURE

ACUTE HAZARDS/ SYMPTOMS

PREVENTION

FIRST AID/
FIRE FIGHTING

FIRE Combustible.
NO open flames.
Water spray. Dry powder. Foam. Carbon dioxide.
EXPLOSION Finely dispersed particles form explosive mixtures in air.
Prevent deposition of dust; closed system, dust explosion-proof electrical equipment and lighting.

EXPOSURE See NOTES.
PREVENT DISPERSION OF DUST!

•INHALATION
Local exhaust or breathing protection.
Fresh air, rest.
•SKIN
Protective gloves.
Remove contaminated clothes. Rinse and then wash skin with water and soap.
•EYES
Safety goggles
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
•INGESTION
Do not eat, drink, or smoke during work.
Rinse mouth.

SPILLAGE DISPOSAL

STORAGE

PACKAGING & LABELLING

Personal protection: P2 filter respirator for harmful particles. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place.
Separated from strong oxidants . Provision to contain effluent from fire extinguishing. Store in an area without drain or sewer access.

UN Hazard Class: 9
UN Packing Group: III
Signal: Warning
Enviro
Very toxic to aquatic life with long lasting effects
ICSC: 1674 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

ACENAPHTHENE

ICSC: 1674

I

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A

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D

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A

PHYSICAL STATE; APPEARANCE:
WHITE TO BEIGE CRYSTALS

PHYSICAL DANGERS:
Dust explosion possible if in powder or granular form, mixed with air.

CHEMICAL DANGERS:
On combustion, forms toxic gases including carbon monoxide. Reacts with strong oxidants .

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.
MAK not established.


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol, through the skin and by ingestion.

INHALATION RISK:
A harmful concentration of airborne particles can be reached quickly when dispersed .

EFFECTS OF SHORT-TERM EXPOSURE:


EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
See Notes.

PHYSICAL
PROPERTIES

Boiling point: 279°C
Melting point: 95°C
Density: 1.2
g/cm3
Solubility in water, g/100 ml at 25°C: 0.0004
Vapour pressure, Pa at 25°C: 0.3
Relative vapour density (air = 1): 5.3
Flash point: 135°C o.c.
Auto-ignition temperature: >450 °C
Octanol/water partition coefficient as log Pow: 3.9 - 4.5

ENVIRONMENTAL
DATA

The substance is very toxic to aquatic organisms. The substance may cause long-term effects in the aquatic environment. It is strongly advised that this substance does not enter the environment.

N O T E S

Acenaphthene occurs as a pure substance and also as a component of polyaromatic hydrocarbon (PAH) mixtures. Human population studies have associated PAH's exposure with cancer and cardiovascular diseases. Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken.
Transport Emergency Card: TEC (R)-90GM7-III

ADDITIONAL INFORMATION



ICSC: 1674 ACENAPHTHENE
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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