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NIOSH

1-HEXANOL

ICSC: 1084

Hexyl alcohol
n-Hexanol
n-Hexyl alcohol
1-Hydroxyhexane
Amyl carbinol
Caproyl alcohol
C6H14O / CH3(CH2)4CH2OH
Molecular mass: 102.2
ICSC # 1084 		CAS # 111-27-3
RTECS # MQ4025000
EC # 603-059-00-6
September 10, 2002 Validated

TYPES OF HAZARD/ EXPOSURE

ACUTE HAZARDS/ SYMPTOMS

PREVENTION

FIRST AID/
FIRE FIGHTING

FIRE Combustible.
NO open flames.
Alcohol-resistant foam, dry powder, carbon dioxide.
EXPLOSION Above 63°C explosive vapour/air mixtures may be formed.
Above 63°C use a closed system, ventilation.
In case of fire: keep drums, etc., cool by spraying with water.
EXPOSURE


•INHALATION Cough. Sore throat.
Ventilation, local exhaust, or breathing protection.
Fresh air, rest.
•SKIN Dry skin.
Protective gloves.
Rinse and then wash skin with water and soap.
•EYES Redness. Pain.
Safety goggles.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
•INGESTION Burning sensation.
Do not eat, drink, or smoke during work.
Rinse mouth. Give one or two glasses of water to drink. Do NOT induce vomiting.

SPILLAGE DISPOSAL

STORAGE

PACKAGING & LABELLING

Collect leaking liquid in covered containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. (Extra personal protection: filter respirator for organic gases and vapours.)
Separated from strong oxidants.

Xn symbol
R: 22
S: (2-)24/25
ICSC: 1084 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

1-HEXANOL

ICSC: 1084

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PHYSICAL STATE; APPEARANCE:
COLOURLESS LIQUID , WITH CHARACTERISTIC ODOUR.

PHYSICAL DANGERS:


CHEMICAL DANGERS:
Reacts with strong oxidants .

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.
MAK: IIb (not established but data is available) (DFG 2008).


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation and by ingestion.

INHALATION RISK:
No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance is irritating to the respiratory tract and the skin . The substance is severely irritating to the eyes . If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
The liquid defats the skin.

PHYSICAL
PROPERTIES

Boiling point: 157°C
Melting point: -44.6°C
Relative density (water = 1): 0.82
Solubility in water, g/100 ml at 20°C: 0.59
Vapour pressure, kPa at 25°C: 0.124
Relative vapour density (air = 1): 3.52
Relative density of the vapour/air-mixture at 20°C (air = 1): 1
Flash point: 63°C c.c.
Auto-ignition temperature: 290°C
Explosive limits, vol% in air: 1.2-7.7 (calculated)
Octanol/water partition coefficient as log Pow: 2.03

ENVIRONMENTAL
DATA


N O T E S

NFPA Code: H1; F2; R0;
Card has been partially updated in November 2008: see Occupational Exposure Limits,

ADDITIONAL INFORMATION



ICSC: 1084 1-HEXANOL
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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