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AMMONIUM CHLORIDE

ICSC: 1051

Sal ammoniac
NH4Cl
Molecular mass: 53.5
ICSC # 1051 		CAS # 12125-02-9
RTECS # BP4550000
EC # 017-014-00-8
December 04, 2000 Validated

TYPES OF HAZARD/ EXPOSURE

ACUTE HAZARDS/ SYMPTOMS

PREVENTION

FIRST AID/
FIRE FIGHTING

FIRE Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.

In case of fire in the surroundings: all extinguishing agents allowed.
EXPLOSION


EXPOSURE


•INHALATION Cough. Sore throat.
Ventilation (not if powder), local exhaust, or breathing protection.
Fresh air, rest. Refer for medical attention.
•SKIN Redness.
Protective gloves.
Remove contaminated clothes. Rinse skin with plenty of water or shower.
•EYES Redness. Pain.
Safety spectacles.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
•INGESTION Nausea. Sore throat. Vomiting.
Do not eat, drink, or smoke during work.
Rinse mouth. Give plenty of water to drink. Rest. Refer for medical attention.

SPILLAGE DISPOSAL

STORAGE

PACKAGING & LABELLING

Sweep spilled substance into containers. Wash away remainder with plenty of water. (Extra personal protection: P2 filter respirator for harmful particles).
Separated from ammonium nitrate, potassium chlorate. Dry.

Xn symbol
R: 22-36
S: 2-22
ICSC: 1051 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

AMMONIUM CHLORIDE

ICSC: 1051

I

M

P

O

R

T

A

N

T


D

A

T

A

PHYSICAL STATE; APPEARANCE:
ODOURLESS, COLOURLESS TO WHITE , HYGROSCOPIC SOLID IN VARIOUS FORMS.

PHYSICAL DANGERS:


CHEMICAL DANGERS:
The substance decomposes on heating producing toxic and irritating fumes (nitrogen oxides, ammonia and hydrogen chloride). The solution in water is a weak acid. Reacts violently with ammonium nitrate and potassium chlorate causing fire and explosion hazard. Attacks copper and its compounds.

OCCUPATIONAL EXPOSURE LIMITS:
TLV (as fume): 10 mg/m3 (as TWA); 20 mg/m3 (as STEL) (ACGIH 1998).
MAK not established.
OSHA PEL†: none
NIOSH REL: TWA 10 mg/m3 ST 20 mg/m3
NIOSH IDLH: N.D. See: IDLH INDEX


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its dust or fume and by ingestion.

INHALATION RISK:
Evaporation at 20°C is negligible; a nuisance-causing concentration of airborne particles can, however, be reached quickly.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance irritates the eyes, the skin and the respiratory tract.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:

PHYSICAL
PROPERTIES

Boiling point: 520°C
Melting point (decomposes): 338°C
Density: 1.5
g/cm3
Solubility in water, g/100 ml at 25°C: 28.3
Vapour pressure, kPa at 160°C: 0.13

ENVIRONMENTAL
DATA

The substance is toxic to aquatic organisms.

N O T E S

NFPA Code: H 1; F 0; R 0;

Transport Emergency Card: TEC (R)-90G02

ADDITIONAL INFORMATION



ICSC: 1051 AMMONIUM CHLORIDE
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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