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SODIUM NITRATE

ICSC: 0185

Chile saltpeter
NaNO3
Molecular mass: 85
ICSC # 0185
CAS # 7631-99-4
RTECS # WC5600000
UN # 1498
October 15, 2001 Validated

TYPES OF HAZARD/ EXPOSURE

ACUTE HAZARDS/ SYMPTOMS

PREVENTION

FIRST AID/
FIRE FIGHTING

FIRE Not combustible but enhances combustion of other substances. Gives off irritating or toxic fumes (or gases) in a fire.
NO contact with combustibles and reducing agents.
In case of fire in the surroundings: use appropriate extinguishing media.
EXPLOSION Risk of fire and explosion on contact with reducing agents.


EXPOSURE
PREVENT DISPERSION OF DUST!

•INHALATION Cough. Sore throat.
Local exhaust or breathing protection.
Fresh air, rest. Refer for medical attention.
•SKIN Redness.
Protective gloves.
First rinse with plenty of water, then remove contaminated clothes and rinse again.
•EYES Redness. Pain.
Safety goggles.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
•INGESTION Abdominal pain. Blue lips or fingernails. Blue skin. Convulsions. Diarrhoea. Dizziness. Headache. Laboured breathing. Confusion. Nausea. Unconsciousness.
Do not eat, drink, or smoke during work. Wash hands before eating.
Rinse mouth. Refer for medical attention.

SPILLAGE DISPOSAL

STORAGE

PACKAGING & LABELLING

Sweep spilled substance into plastic or glass containers. Wash away remainder with plenty of water.
Separated from combustible and reducing substances. Dry.

UN Hazard Class: 5.1
UN Packing Group: III
ICSC: 0185 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

SODIUM NITRATE

ICSC: 0185

I

M

P

O

R

T

A

N

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D

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A

PHYSICAL STATE; APPEARANCE:
COLOURLESS HYGROSCOPIC CRYSTALS .

PHYSICAL DANGERS:


CHEMICAL DANGERS:
The substance decomposes on heating producing nitrogen oxides and oxygen , which increases fire hazard. The substance is a strong oxidant and reacts with combustible and reducing materials, causing fire and explosion hazard.

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

INHALATION RISK:
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quicklywhen dispersed.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance is irritating to the eyes , the skin and the respiratory tract . The substance may cause effects on the blood , resulting in formation of methaemoglobin when ingested. The effects may be delayed. Medical observation is indicated.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:

PHYSICAL
PROPERTIES

Boiling point (decomposes): 380°C
Melting point: 308°C
Density: 2.3
g/cm3
Solubility in water, g/100 ml at 25°C: 92.1

ENVIRONMENTAL
DATA


N O T E S

Rinse contaminated clothes (fire hazard) with plenty of water. Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.
Transport Emergency Card: TEC (R)-51S1498

ADDITIONAL INFORMATION



ICSC: 0185 SODIUM NITRATE
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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