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NIOSH

ALLYL GLYCIDYL ETHER

ICSC: 0096

((2-Propenyloxy)methyl)oxirane
Allyl 2,3-epoxypropyl ether
1-(Allyloxy)-2,3-epoxypropane
C6H10O2
Molecular mass: 114.2
ICSC # 0096 		CAS # 106-92-3
RTECS # RR0875000
UN # 2219
EC # 603-038-00-1
March 25, 1996 Validated

TYPES OF HAZARD/ EXPOSURE

ACUTE HAZARDS/ SYMPTOMS

PREVENTION

FIRST AID/
FIRE FIGHTING

FIRE Flammable.
NO open flames, NO sparks, and NO smoking.
Powder, AFFF, foam, carbon dioxide.
EXPLOSION Above 48°C explosive vapour/air mixtures may be formed.
Above 48°C use a closed system, ventilation, and explosion-proof electrical equipment.
In case of fire: keep drums, etc., cool by spraying with water.
EXPOSURE
AVOID ALL CONTACT!

•INHALATION Burning sensation. Shortness of breath. Headache. Drowsiness. Dullness. Nausea. Vomiting.
Ventilation, local exhaust, or breathing protection.
Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.
•SKIN MAY BE ABSORBED! Dry skin. Redness. Pain. Blisters.
Protective gloves. Protective clothing.
Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.
•EYES Redness. Pain. Blurred vision. Severe deep burns.
Safety goggles or face shield .
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
•INGESTION Burning sensation. Headache. Dullness. Drowsiness. Nausea. Vomiting.
Do not eat, drink, or smoke during work.
Rinse mouth. Give plenty of water to drink. Refer for medical attention.

SPILLAGE DISPOSAL

STORAGE

PACKAGING & LABELLING

Ventilation. Collect leaking and spilled liquid in sealable containers as far as possible. Wash away remainder with plenty of water. Personal protection: self-contained breathing apparatus.
Fireproof. Separated from strong oxidants, strong bases, strong acids. Cool. Keep in the dark.

Xn symbol
R: 10-20/22-37/38-40-41-43-52/53-62-68
S: 2-24/25-26-36/37/39-61
UN Hazard Class: 3
UN Subsidiary Risks: 6.1
UN Packing Group: III
ICSC: 0096 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 1994. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

ALLYL GLYCIDYL ETHER

ICSC: 0096

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PHYSICAL STATE; APPEARANCE:
COLOURLESS LIQUID , WITH CHARACTERISTIC ODOUR.

PHYSICAL DANGERS:


CHEMICAL DANGERS:
The substance can presumably form explosive peroxides. The substance may polymerize readily. The substance decomposes on burning producing toxic gases . Reacts violently with strong oxidants , acids and bases .

OCCUPATIONAL EXPOSURE LIMITS:
TLV: 1 ppm as TWA; A4 (not classifiable as a human carcinogen); (ACGIH 2004).
MAK: skin absorption (H); sensitization of skin (Sh);
Carcinogen category: 2;
(DFG 2004).
OSHA PEL†: C 10 ppm (45 mg/m3)
NIOSH REL: TWA 5 ppm (22 mg/m3) ST 10 ppm (44 mg/m3) skin
NIOSH IDLH: 50 ppm See: 106923


ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation and through the skin, and by ingestion.

INHALATION RISK:
A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20°C.

EFFECTS OF SHORT-TERM EXPOSURE:
Corrosive. The substance is corrosive to the eyes, the skin and the respiratory tract. Inhalation of the vapour may cause lung oedema (see Notes). Acute exposure may cause central nervous system depression. Exposure could cause lowering of consciousness. Medical observation is indicated.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
Repeated or prolonged contact with skin may cause dermatitis. Repeated or prolonged contact may cause skin sensitization. May cause genetic damage in humans. Does cause serious reproductive toxicity in humans.

PHYSICAL
PROPERTIES

Boiling point: 154°C
Melting point: -100°C
Relative density (water = 1): 0.97
Solubility in water, g/100 ml: 14
Vapour pressure, kPa at 25°C: 0.63
Relative vapour density (air = 1): 3.9
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.02
Flash point: 48°C o.c.
Auto-ignition temperature: see Notes
Explosive limits, vol% in air: see Notes

ENVIRONMENTAL
DATA


N O T E S

Auto-ignition temperature is unknown in literature. Explosive limits are unknown in literature, although the substance is combustible and has a flash point < 61°C. Use of alcoholic beverages enhances the harmful effect. Depending on the degree of exposure, periodic medical examination is suggested. The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential. The odour warning when the exposure limit value is exceeded is insufficient. Check for peroxides prior to distillation; eliminate if found. Card has been partly updated in October 2005. See sections Occupational Exposure Limits, EU classification, Emergency Response.
Transport Emergency Card: TEC (R)-30S2219

ADDITIONAL INFORMATION



ICSC: 0096 ALLYL GLYCIDYL ETHER
(C) IPCS, CEC, 1994
IMPORTANT LEGAL NOTICE: Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.
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